3M CANADA INC -- TROUBLE SHOOTER, CN-1006-1045-6 -- 7930-01-070-2330
===================== Product Identification ===================== Product ID:TROUBLE SHOOTER, CN-1006-1045-6 MSDS Date:11/09/1988 FSC:7930 NIIN:01-070-2330 === Responsible Party === Company Name:3M CANADA INC Address:1840 OXFORD ST E Box:5757 City:LONDON, ONTARIO, N6A 4T1 Info Phone Num:519-452-6146 Emergency Phone Num:519-451-2500 EXT 2222 CAGE:09581 === Contractor Identification === Company Name:3M CANADA INC Address:1840 OXFORD ST E Box:City:LONDON N5V 3R6 State:ON Country:US Phone:519-451-2500 CAGE:09581 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL) LD50: (ORAL, RAT) 530 MG/KG CAS:111-76-2 RTECS #:KJ8575000 Fraction by Wt: 14% OSHA PEL:50 PPM, S ACGIH TLV:25 PPM, S Ingred Name:ETHANOL, 2-AMINO-; (ETHANOLAMINE) LD50: (ORAL, RAT) 2050 MG/KG CAS:141-43-5 RTECS #:KJ5775000 Fraction by Wt: 5% OSHA PEL:3 PPM ACGIH TLV:3 PPM; 6 STEL Ingred Name:NON-IONIC SURFACTANT Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 70-75% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:PROPANE CAS:74-98-6 RTECS #:TX2275000 Fraction by Wt: 8% OSHA PEL:1000 PPM ACGIH TLV:ASPHYXIANT Ingred Name:SMECTITE; (CLAY) CAS:12199-37-0 Fraction by Wt: 1% OSHA PEL:N/K ACGIH TLV:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENTS Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRIT. SYMPS MAY INCL TRANSIENT CONJ IRRIT & MINIMAL CORNEAL OPACITY. MOD IRRIT TO EYES OF ALBINO RABBITS WHEN SPRAYED DIRECTLY INTO EYES FOR 2 SEC FROM DIST OF 4 IN. SKIN:MAY CAUSE MI LD IRRIT. INHAL: HIGH CONCS OF VAPS MAYCAUSE RESP SYS IRRIT & TEMPORARY NERVOUS SYS IMPAIRMENT. SYMPS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: MAY INCL COUGH, HDCH, NAUS, VOMIT, DIZZ & DISCOMFORT TO NOSE, THROAT & CHEST. INGEST: MAY CAUSE DIGESTIVE SYS IRRIT, LIVER & KIDNEY INJURY. SYMPS MAY INCL HDCH, ABDOMINAL PAIN, NAUS, VOMIT & WEAK. CHRONIC: ANIMAL STUDIES HAVE CLEARLY SHOWN DOSE-RELATED ADVERSE EFTS TO CNS, HEMATOPOIETIC TISS, BLOOD, (SUPDAT) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER. CONTINUE FOR AT LEAST 15 MINUTES HOLDING EYELIDS OPEN. CALL MD. SKIN: WASH AFFECTED AREA WITH SOAP & WATER. INHALATION: IF SYMPTOMS OCCUR, REMOVE PER SON TO FRESH AIR. IF SYMPTOMS CONTINUE,CALL MD. INGESTION: DO NOT INDUCE VOMITING. IMMEDIATELY CALL MD. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:196F,91C Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . TREAT AS A PRESSURIZED CONTAINER. Unusual Fire/Explosion Hazard:COMBUSTIBLE. TREAT AS A PRESSURIZED CONTAINER. ================== Accidental Release Measures ================== Spill Release Procedures:IF ANY CANS RUPTURE, EXTINGUISH ALL IGNITION SOURCES & VENTILATE AREA. OBSERVE PRECAUTIONS FROM OTHER SECTIONS. USE ABSORBENT MATERIAL AS NEEDED IN CLEAN-UP PROCEDURE. PLACE CANS IN DOT APPROVED CONTA INER & SEAL. WASH DOWN AREA WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & FLAME. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR STORE ABOVE 120F (49C). KEEP OUT OF THE REACH OF CHILDREN. Other Precautions:AVOID DIRECT EYE CONTACT. AVOID PROLONGED AND REPEATED BREATHING OF VAPORS OR SPRAY. AVOID PROLONGED AND REPEATED SKIN CONTACT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:USE ONLY IN AREAS W/SUFFICIENT VENTILATION TO MAINTAIN VAPOR CONCENTRATIONS BELOW THE RECOMMENDED EXPOSURE LIMITS. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA . Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 11.60-12.00. EFTS OF OVEREXP: KIDNEYS & LIVER ASSOC W/ADMIN OF 2-BUTOXYETHANOL. (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118) . 2-BUTOXYETHANOL, BY SKIN ABSORPTION OR INGESTION, MAY C AUSE BLOOD CHANGES BASED ON ANIMAL STUDIES. WASTE DISP PROC: APPLIC FED, STATE & LOCAL REGS/AUTHS BEFORE DISPOSAL. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Spec Gravity:1.0 (H*2O=1) pH:SUPDAT Solubility in Water:COMPLETE Appearance and Odor:WHITE, FOAMY VISCOUS LIQUID; BLAND ODOR. Percent Volatiles by Volume:98 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES NONE SPECIFIED BY MANUFACTURER. Stability Condition to Avoid:DO NOT STORE ABOVE 120F (49C). Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND SMOKE PARTICLES. ==================== Disposal Considerations ==================== Waste Disposal Methods:DO NOT PUNCTURE/BURN CANS IN HOUSEHOLD INCIN. INCIN IN PERMITTED HAZ WASTE FACILITY THAT CAN HANDLE AEROSOL CANS SAFELY. EMPTY CNTNR MAY BE SANITARY LANDFILLED. CAN CONTENTS MAY BE BLED INTO WASTEWATE R TREATMENT SYS. SINCE REGS VARY, CONSULT (SUPDAT) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.